CAS Number:
11138-66-2
Chemical / IUPAC Name:
Xanthan gum is a high molecular weight polysaccharide produced by fermentation. It contains D-glucose, D-mannose, D-glucuronic acid, and pyruvic acid, and is prepared as the sodium, potassium, or calcium salt
INCI Name:
Xanthan Gum
EC Number:
234-394-2
Molecular Formula:
(C35H49O29)n
Molecular Weight:
Approximately 1,000,000 daltons
Other Names:
Corn sugar gum, bacterial polysaccharide
Uses:
Xanthan gum is a high molecular weight polysaccharide produced by fermenting carbohydrates with the bacterium Xanthomonas campestris . It is a cream-colored powder that dissolves in water to form a viscous solution, functioning as a powerful thickener, stabilizer, and emulsifier .
· Cosmetics & Personal Care: Used in lotions, creams, gels, shampoos, conditioners, and toothpaste as a thickener, stabilizer, and suspension agent. It improves texture, provides smooth application, and stabilizes emulsions .
· Hair Care: Provides viscosity and improves spreadability in styling gels, conditioners, and other hair products .
· Skin Care: Creates a pleasant, smooth feel in serums, creams, and masks. It helps stabilize formulations and can suspend insoluble ingredients.
· Pharmaceuticals: Used in oral and topical formulations as a suspending and thickening agent . It is also used to thicken liquids for individuals with swallowing difficulties (dysphagia) .
· Food Industry: Functions as a thickener, stabilizer, and emulsifier (food additive E415) in salad dressings, sauces, dairy products, ice cream, gluten-free baked goods, and beverages .
· Industrial Applications: Used in water-based paints, drilling fluids, and agricultural products as a rheology modifier.
Origin
Xanthan gum is a natural polysaccharide produced by microbial fermentation. The manufacturing process involves:
· Fermentation: Pure-culture fermentation of a carbohydrate (glucose, sucrose, or lactose from sources like corn, wheat, soy, or dairy) with the bacterium Xanthomonas campestris .
· Purification: The fermented mixture is pasteurized and purified by recovery with ethanol or propan-2-ol to kill the bacteria and isolate the gum .
· Drying & Milling: The purified gum is dried and milled into a fine, cream-colored powder .
What does Xanthan Gum Powder do in a formulation?
- Thickener / Viscosity Modifier: Dramatically increases the viscosity of aqueous systems at low concentrations (typically 0.1-2%), improving product consistency .
- Emulsion Stabilizer: Helps stabilize oil-in-water emulsions, preventing separation of ingredients .
- Suspending Agent: Keeps insoluble particles suspended in liquid formulations, preventing settling.
- Rheology Modifier: Imparts pseudoplastic (shear-thinning) behavior, meaning it thickens when at rest but flows easily when shaken or applied.
- Binding Agent: Helps hold ingredients together and improves texture.
- Film-Former: Creates a thin, protective film on skin or hair.
Safety Profile:
· General Hazard Classification: Non-hazardous. Xanthan gum is not classified as a dangerous substance according to GHS regulations . It has been FDA-approved since 1969 and is GRAS (Generally Recognized as Safe) for food use .
· Toxicity: Low acute toxicity. The Joint Expert Committee on Food Additives (JECFA) assigned an acceptable daily intake of "not specified" .
· Irritation & Sensitization: Generally regarded as non-irritating and non-sensitizing to skin. May cause mild eye irritation upon direct contact . Inhalation of dust may cause respiratory tract irritation .
· Ingestion Safety: Considered safe for consumption. May cause digestive issues like gas or bloating if consumed in very large amounts .
· Allergen Considerations: While highly purified, individuals with severe allergies to corn, wheat, soy, or dairy may react to xanthan gum produced from these sources .
· Microbiological Purity: Must meet strict standards: Total plate count ≤ 5000 CFU/g, yeasts/molds ≤ 300 CFU/g, Salmonella/E. coli absent .
· Storage: Store in a cool, dry place away from direct sunlight. Protect from moisture as it will coagulate and become difficult to dissolve .
· Shelf Life: Typically 2-5 years when stored properly .
· Regulatory Status: Approved worldwide as food additive E415 . Meets USP, BP, and Ph.Eur. pharmacopoeia standards . Halal and Kosher certified options available .
Technical profile:
| Property | Values |
| Appearance | Cream-colored to white or light yellow, free-flowing powder |
| Odor | Slight, characteristic |
| Assay (Purity) | 91.0 – 108.0% (on dry basis) |
| Loss on Drying | ≤ 12-15% |
| Total Ash | 6.5 – 16.0% |
| Pyruvic Acid | ≥ 1.5% |
| Nitrogen Content | ≤ 1.5% |
| Heavy Metals (as Pb) | ≤ 20 ppm |
| Lead (Pb) | ≤ 2-5 mg/kg |
| Arsenic (As) | ≤ 2-3 mg/kg |
| Alcohol Residue | ≤ 500 mg/kg (ethanol and propan-2-ol, singly or in combination) |
| pH (1% solution) | 6.0 – 8.0 (neutral) |
| Viscosity | (1% in 1% KCl) 1200 – 1700 cP (typical food grade); can be as low as 600 cP depending on grade |
| Particle Size | 80 mesh: min. 100% through; 200 mesh: min. 92-95% through |
| Bulk Density | 550 – 850 kg/m³ |
| Solubility | Soluble in water (forms clear to hazy viscous solutions); insoluble in ethanol and oils |
| Melting Point | Not applicable (decomposes) |
| Boiling Point | Not applicable |
| Flash Point | Not applicable (dust may form explosive mixtures) |
| Stability | Stable under normal temperatures and pressures; stable at pH 3–11; heat stable up to 80°C |
| V1/V2 (Shear Ratio) | 1.02 – 1.45 |
| Recommended Use Level | 0.1 – 2.0% in cosmetic and food formulations |