CAS Number:
100-51-6
Chem/ INCI Name:
Benzyl Alcohol
Common Synonyms:
Phenylmethanol, Benzenemethanol
Molecular Formula:
C7H8O
Molecular Weight:
108.14 g/mol
Uses:
Benzyl alcohol is a colorless liquid with a mild, pleasant aroma. It functions as an effective broad-spectrum antimicrobial preservative and a versatile solvent. Its primary applications are in:
· Cosmetics & Personal Care: Used as a preservative (typically at 0.5% to 2%) in creams, lotions, shampoos, and serums to prevent microbial growth. It is also used as a fragrance ingredient and solvent.
· Pharmaceuticals: Serves as a bacteriostatic preservative in intravenous medications and topical drugs.
· Industrial Applications: A common solvent for inks, paints, lacquers, and epoxy resin coatings. It is also a key precursor in the synthesis of various esters for perfumes and flavors.
Origin:
It can be found naturally in some fruits and teas. Synthetically, it is produced industrially from toluene, often via benzyl chloride hydrolysis or benzaldehyde hydrogenation.
What does Benzyl Alcohol do in a formulation?
As defined by SpecialChem, its primary functions are: Antimicrobial, Preservative, Perfuming, Solvent, and Viscosity Controlling.
Safety Profile:
· General Safety: Recognized as safe for use in cosmetics and personal care products within recommended concentrations (often up to 2% as a preservative).
· Irritation & Sensitization: Considered one of the least sensitizing preservatives, though high concentrations can be drying or irritating. Hazard classifications typically include warnings for being harmful if swallowed and causing serious eye irritation.
· Critical Restrictions: Toxic to neonates (associated with "gasping syndrome") and must be avoided in products for this group. Its preservative efficacy is limited to formulations with a pH below 5.5. In perfumery, its use is restricted (e.g., to 2.5% in certain categories) due to sensitization potential.
Technical profile:
| Property | Values |
| Appearance | Colorless to pale yellow clear liquid |
| Purity/Assay | Available as ≥95%, >99.0%(GC), or 99.8% (anhydrous) |
| Odor | Slightly aromatic, pleasant |
| Density | ~1.045 g/mL at 25°C |
| Refractive Index | ~1.539 |
| Boiling Point | 203-205 °C |
| Melting Point | -15 °C to -13 °C |
| Solubility | Soluble in water (~40 g/L at 20°C). Miscible with alcohol, ether, and chloroform |
| Flash Point | ~101 °C (closed cup) |
| pH | Approximately neutral (pH 7.0 for pure substance) |