CAS Number:
7758-29-4
Chemical / IUPAC Name:
Pentasodium triphosphate
INCI Name:
Pentasodium Triphosphate (used in cosmetics); Sodium Tripolyphosphate (general)
EC Number:
231-838-7
Molecular Formula:
Na5P3O10
Molecular Weight:
367.86 g/mol
Other Names:
STPP, Sodium triphosphate, Sodium polyphosphate, E451(i)
Uses:
Food Grade Sodium Tripolyphosphate (STPP) is an inorganic salt and highly purified form of sodium triphosphate, appearing as a white, free-flowing powder or granules . It meets strict food safety standards (FCC, GRAS) and is widely used as a multifunctional food additive (E451i) .
· Meat, Poultry & Seafood Processing: Used as a moisture retention agent and water binder in processed meats, ham, sausages, and seafood. It increases the water-holding capacity of muscle proteins, reducing drip loss during thawing and cooking, resulting in juicier, plumper products with higher yield .
· Dairy & Processed Foods: Functions as an emulsifier and stabilizer in processed cheese, cheese spreads, and dairy products to prevent fat separation and ensure smooth melting .
· Canned Foods & Beverages: Acts as a quality improver in canned vegetables (softens bean skins), canned ham (tenderizes meat), and fruit juice drinks to maintain texture and stability .
· Seafood Preservation: Helps retain moisture in frozen shrimp, fish fillets, and other seafood during freezing and thawing, reducing weight loss and improving texture .
· Noodles & Pasta: Used to improve texture and reduce cooking loss in fresh and dried noodle products .
Origin
STPP is produced industrially by reacting thermal phosphoric acid (or highly purified wet phosphoric acid) with soda ash (sodium carbonate) . The resulting orthophosphate mixture is spray-dried or crystallized, then heated under carefully controlled conditions to permit polymerization into sodium tripolyphosphate .
What does STPP Food Grade do in a formulation?
- Moisture Retention Agent: Enhances water-binding capacity of proteins in meat and seafood, reducing moisture loss during processing, freezing, and cooking .
- Sequestrant / Chelating Agent: Binds multivalent metal ions (calcium, magnesium, iron, copper), preventing them from catalyzing oxidation reactions or forming insoluble precipitates .
- Emulsifier: Helps stabilize oil-in-water emulsions in processed cheese, sauces, and other food products .
- pH Buffer: Maintains optimal acidity in formulations; 1% aqueous solution has pH 9.5-10.0 .
- Texture Enhancer: Improves tenderness in meats and softens skins of legumes in canned products
- Antioxidant Synergist: Stabilizes iron and copper in their oxidized states, inhibiting lipid oxidation and rancidity in meat and emulsified systems .
Safety Profile:
· GRAS Status: Generally Recognized as Safe (GRAS) by the U.S. FDA for use in food when used in accordance with Good Manufacturing Practice (21 CFR 182.6810) . EU approved as food additive E451(i) .
· Concentration Limits: Usage levels vary by food category (typically 0.1-0.5%). Maximum permitted levels range from 900-5000 mg/kg depending on the specific food product (as phosphorus pentoxide or total phosphate) .
· Toxicity: Low acute toxicity. Acceptable Daily Intake (ADI) established by JECFA.
· Health Consideration: Excessive intake may contribute to elevated phosphorus levels in individuals with kidney disease; should be used within regulatory limits .
· Irritation & Sensitization: May cause mild eye or skin irritation upon direct contact with concentrated powder. Dust may irritate respiratory tract.
· Handling & Storage: Store in a cool, dry place in tightly sealed containers. Protect from moisture as it is hygroscopic. Keep away from acids .
· Regulatory Status: Meets FCC, Food Grade standards, and various pharmacopoeia specifications. Compliant with FDA, EFSA, and WHO food additive requirements .
Technical profile:
| Property | Values |
| Appearance | White, free-flowing powder or granules |
| Assay (Na?P?O??) | ≥ 95.0% (typical) |
| P?O? Content | ≥ 57.0% |
| Water Insoluble Matter | ≤ 0.05% |
| pH (1% solution) | 9.5 – 10.0 |
| Heavy Metals (as Pb) | ≤ 10 ppm (0.001%) |
| Arsenic (As) | ≤ 1-3 ppm (0.0001-0.0003%) |
| Fluoride (F) | ≤ 30 ppm (0.003%) |
| Iron (Fe) | ≤ 10-50 ppm |
| Chloride (Cl) | ≤ 100 ppm |
| Sulfate (SO?) | ≤ 10-100 ppm |
| Whiteness | ≥ 90% |
| Loss on Drying | ≤ 0.5% |
| Bulk Density | 0.35 – 0.9 g/cm³ (varies by grade: low, medium, high density) |
| Melting Point | 622°C |
| Solubility | Soluble in water; slightly soluble in alcohol |
| Crystal Forms | Type I (high temperature) and Type II (low temperature) |
| Stability | Stable under recommended storage conditions; hygroscopic |
| Shelf Life | 24 months when stored properly in sealed containers |
| Recommended Use Level | 0.1 – 0.5% in most food applications (varies by product category and regulations) |