CAS Number:
10213-79-3
Chemical Name:
Sodium Metasilicate Pentahydrate
Molecular Formula:
Na2SiO3·5H2O. It is often written as Na2SiO2(OH)2·4H2O in its hydrated form.
Molecular Weight:
212.14 g/mol (for the pentahydrate). The anhydrous form is 122.06 g/mol
Common Form:
White crystalline granules, beads, or powder. It is hygroscopic and deliquescent (absorbs moisture from air)
Uses:
It is a strong alkaline builder and multifunctional additive prized for its cleaning, corrosion inhibition, and buffering properties.
Primary Applications:
· Detergents & Cleaners: A key builder in industrial and household detergents, soaps, metal cleaners, and degreasers. It emulsifies fats, disperses dirt, and softens water.
· Metal Surface Treatment: Used in metal cleaning and as a corrosion inhibitor, forming a protective layer on metals like aluminum and zinc.
· Ceramics & Cement: Acts as a deflocculant to improve slurry fluidity in ceramics and as a coagulant in acid-resistant cement and concrete.
· Pulp, Paper & Textiles: Used in paper deinking, as a bleach stabilizer for hydrogen peroxide, and as a pretreatment agent in textiles.
· Other Industries: Egg preservation, fireproofing materials, water treatment, and as a raw material for silica gel and zeolites.
What does Sodium Metasilicate Pentahydrate do in a formulation?
- Strong Alkali & pH Buffer: Provides and maintains high alkalinity (pH ~12-13 for a 1% solution), which is crucial for saponifying fats and oils
- Builder & Water Softener: Sequesters hardness ions (calcium, magnesium) to enhance surfactant performance.
- Corrosion Inhibitor: The silicate component forms a passive protective layer on metal surfaces, reducing corrosion.
- Dispersant & Antiredeposition Agent: Keeps soils and particles suspended in solution, preventing them from redepositing onto cleaned surfaces.
- Key Differentiator: Considered less aggressive on metals and surfaces than caustic soda (NaOH) while providing similar alkalinity, due to its protective silicate film.
Safety Profile:
· Hazard Classification: Danger. Causes severe skin burns, serious eye damage, and may cause respiratory irritation.
· Skin/Eye Exposure: Highly corrosive. Causes severe burns. Requires immediate and prolonged rinsing with water and medical attention.
· Required PPE: Essential. Chemical safety goggles, face shield, acid/alkali-resistant gloves, and protective clothing are mandatory. Use in a well-ventilated area or with respiratory protection to avoid dust inhalation.
· Handling & Storage: Store in a cool, dry, sealed container to prevent absorption of moisture and CO? from air. Always add solid to water slowly while stirring to control heat and splashing.
Technical profile:
| Property | Values |
| Appearance | White granules or powder |
| Bulk Density | 0.8 - 1.0 g/cm³ (granular form). True density is ~2.61 g/cm³ |
| pH (1% solution) | 12.0 - 13.0 |
| Solubility | Highly soluble in cold water. Insoluble in alcohol and acids |
| Melting Point | ~72°C for the pentahydrate (with dehydration); 1088°C for the anhydrous compound |
| Typical Purity/Composition | · Sodium Oxide (Na?O): 28.0 - 30.0%. · Silicon Dioxide (SiO?): 27.8 - 29.5%. · Water Insoluble Matter: ≤ 0.05%. |