CAS Number:
25322-68-3 (general PEG CAS)
Chemical / INCI Name:
PEG-90M
Molecular Formula:
H(OCH2CH2)nOH, where n is approximately 90,000
Molecular Weight:
~ 4,000,000 g/mol (4 million)
Other Names:
Polyethylene Glycol 90M, Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy- (molecular weight approx. 4,000,000), Ultra-high molecular weight PEG
Uses:
PEG-90M is an ultra-high molecular weight polyethylene glycol. Its extremely long polymer chains give it unique rheological properties, making it an exceptional thickener, lubricant, and film former .
· Personal Care & Cosmetics: Used in shaving creams, shaving gels, depilatory products, and facial masks to provide a smooth, lubricious glide and prevent irritation during shaving or hair removal .
· Skin Care: Functions as a film former and viscosity modifier in gels, masks, and serums, providing a unique, silky skin feel .
· Hair Care: Used in styling products to provide hold and conditioning .
· Industrial Applications: Functions as a lubricant, binder, and release agent in ceramics, metalworking, and construction materials .
Origin
PEG-90M is a synthetic polymer produced by the polymerization of ethylene oxide. The "90M" designation indicates a very high molecular weight (approximately 4 million g/mol), achieved through specialized polymerization processes .
What does PEG-90M do in a formulation?
- Viscosity Modifier / Thickener: Provides exceptional thickening at very low concentrations .
- Lubricant: Creates a smooth, slippery, lubricious feel, ideal for shaving products .
- Film Former: Forms a continuous, flexible film on skin or hair .
- Binder: Helps hold ingredients together in solid formulations .
- Water Retention Agent: Helps retain moisture in formulations .
Safety Profile:
· General Hazard Classification: Considered safe for use in cosmetics at typical concentrations .
· Molecular Weight Consideration: High molecular weight PEGs like PEG-90M are not significantly absorbed through the skin due to their large molecular size .
· Purity: High molecular weight PEGs are typically well-purified. Concerns about ethylene oxide or 1,4-dioxane contamination are minimal with high-quality, cosmetic-grade materials .
· Irritation & Sensitization: Generally regarded as non-irritating and non-sensitizing at typical use concentrations .
· Biodegradability: High molecular weight PEGs are less readily biodegradable than low molecular weight PEGs .
· Regulatory Status: Approved for use in cosmetics worldwide .
Technical profile:
| Property | Values |
| Appearance | White to off-white powder or granular solid |
| Odor | Odorless or faint characteristic odor |
| Viscosity (5% solution) | 40,000 - 70,000 mPa·s (cP) at 25°C |
| pH (5% solution) | 5.0 - 7.5 |
| Water Content | ≤ 1.0% |
| Residue on Ignition | ≤ 1.0% |
| Bulk Density | ~0.3 - 0.6 g/cm³ |
| Melting Point | 62 - 67°C (144-153°F) |
| Flash Point | 240°C (> 464°F) |
| Solubility | Soluble in water, alcohol, and glycols; insoluble in oils |
| Melting Point | 200°C (decomposes) |
| Stability | soluble in water, alcohol, and glycols; insoluble in oils |
| Recommended Use Level | 0.1 - 2.0% in cosmetic formulations (effective at very low concentrations) |