CAS Number:
7664-38-2
Chemical Name:
Phosphoric Acid (Orthophosphoric Acid)
Common Concentration:
85% (by weight) in water is the standard technical and food-grade concentration
Molecular Formula:
H3PO4
Molecular Weight:
98.00 g/mol (anhydrous)
Common Form:
Clear, colorless, odorless, syrupy liquid
Uses:
Phosphoric acid is a strong, non-volatile, inorganic acid with triple acidity. Its 85% concentration is the workhorse grade for industrial and food applications due to its stability and handling properties.
Primary Applications:
· Fertilizer Industry (>90% of global use): Raw material for producing phosphate fertilizers (e.g., ammonium phosphates, superphosphates).
· Food & Beverage Industry (E338): Acidulant and pH adjuster in cola beverages, jams, processed meats, and cheese. Provides a sharp, sour taste.
· Metal Treatment & Cleaning: Key component in solutions for rust removal, phosphating (creating a corrosion-resistant coating on steel), and metal cleaning/pickling.
· Water Treatment: Used for pH adjustment/correction and as a sequestrant to control scale (e.g., in potable water systems).
· Chemical Manufacturing: Precursor to other phosphate compounds like sodium phosphates (STPP, etc.), and used in catalysts, dyes, and fire retardants.
· Dentistry: Etching agent for tooth enamel in dental procedures.
What does Phosphoric Acid (85%) do in a formulation?
- Acidulant & pH Controller: Provides a strongly acidic medium (pH of 85% solution is <1.0; 1% solution ~1.5). Its non-volatile nature makes it ideal for long-term pH control
- Sequestering Agent: Binds metal ions like calcium and magnesium, preventing precipitation and scale formation.
- Catalyst: Used as an acid catalyst in organic synthesis (e.g., petroleum alkylation)
- Etchant & Cleaning Agent: Reacts with metal oxides to dissolve rust and etches surfaces for better adhesion
- Flavor Enhancer: Imparts a characteristic tartness in foods and beverages.
- Nutrient Source: Provides phosphorus in fertilizers and some food fortification.
Safety Profile:
· Hazard Classification: Danger. Causes severe skin burns and eye damage. May be corrosive to metals.
· Skin/Eye Contact: Extremely corrosive. Causes immediate tissue damage and severe chemical burns. Flush immediately with plenty of water for at least 15-20 minutes and seek medical attention.
· Inhalation: Mist or vapors from hot solutions can irritate the nose, throat, and respiratory tract, causing coughing and shortness of breath.
· Ingestion: Highly corrosive. Can cause severe burns of the mouth, throat, and stomach, with potential for perforation. Do NOT induce vomiting.
· Required PPE: Chemical-resistant gloves (e.g., neoprene, nitrile), splash goggles or face shield, acid-resistant apron or clothing, and adequate ventilation.
· Handling Note: ALWAYS add acid to water slowly with stirring, NEVER water to acid, to prevent violent exothermic reaction and splattering of concentrated acid. Store away from bases and metals.
Technical profile:
| Property | Values |
| Appearance | Clear, colorless, viscous liquid |
| Assay (Purity) | Typically 85.0% ± 1.0% H?PO? |
| Specific Gravity (25°C) | ~1.685 |
| pH (as supplied) | < 1.0 |
| Freezing Point | ~21°C. Can solidify in cold storage |
| Boiling Point | ~158°C (decomposes) |
| Viscosity | Very high (syrupy) due to hydrogen bonding |
| Common Impurities | Traces of arsenic, fluoride, chloride, sulfate, and heavy metals (limits are stricter for food grade). |